Transfer Reduction of Aryl Chlorides with Potassium Formate in Water Using Polymer-Supported Terpyridine Palladium Complex

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Reactivity of Aryl Halides for Reductive Dehalogenation in (Sea)water Using Polymer-Supported Terpyridine Palladium Catalyst.

A polymer-supported terpyridine palladium complex was prepared. The complex was found to promote hydrodechlorination of aryl chlorides with potassium formate in seawater. Generally, reductive cleavage of aryl chlorides using transition metal catalysts is more difficult than that of aryl bromides and iodides (reactivity: I > Br > Cl); however, the results obtained did not follow the general tren...

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Reusable Polymer-Supported Terpyridine Palladium Complex for Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost Reaction in Water

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ژورنال

عنوان ژورنال: Transactions of the Materials Research Society of Japan

سال: 2014

ISSN: 1382-3469,2188-1650

DOI: 10.14723/tmrsj.39.235